New Patterns in Steady-State Chemical Kinetics: Intersections, Coincidences, Map of Events (Two-Step Mechanism)

作者：Pinto Daniel Branco^*; Yablonsky Gregory; Marin Guy B; Constales Denis

来源：Entropy, 2015, 17(10): 6783-6800.

DOI：10.3390/e17106783

• chemical kinetics
• kinetic parameters
• CSTR
• patterns
• two-step mechanism
• intersections
• coincidences
• maxima

New patterns of steady-state chemical kinetics for continuously stirred-tank reactors (CSTR) have been found, i.e., intersections, maxima and coincidences, for two-step mechanism ABC. There were found elegant analytical relationships for characteristics of these patterns (space times, values of concentrations and rates) allowing kinetic parameters to be easily determined. It was demonstrated that for the pair of species involved into the irreversible reaction (B and C), the space time of their corresponding concentration dependence intersection is invariant and does not depend on the initial conditions of the system. Maps of patterns are presented for visualization of their combinations and ranking in space time, and values of concentration and rates.

• 出版日期2015-10