High propylene/propane adsorption selectivity in a copper(catecholate)-decorated porous organic polymer

作者:Weston Mitchell H; Colon Yamil J; Bae Youn Sang; Garibay Sergio J; Snurr Randall Q; Farha Omar K*; Hupp Joseph T; Nguyen SonBinh T
来源:Journal of Materials Chemistry A, 2014, 2(2): 299-302.
DOI:10.1039/c3ta12999c

摘要

A porous organic polymer decorated with high densities of copper(catecholate) groups was prepared and characterized. Single-component propylene and propane isotherms measured at ambient temperatures and ideal adsorption solution theory (IAST) calculations revealed increasing propylene/propane selectivities with increasing pressures.