New Process of 2-Nitrotoluene into 2-Methylaniline by Transfer Hydrogenation with Methanol over X Zeolite Catalyst

作者：Zhao, Guoqing; Chen, Huanhui; Yuan, Ying; Li, Xiaoci; Zhu, Zhirong^*

来源：Catalysis Letters, 2016, 146(1): 174-179.

DOI：10.1007/s10562-015-1633-1

• Transfer hydrogenation
• Methanol
• X zeolite
• 2-Nitrotoluene
• 2-Methylaniline

A new transfer hydrogenation of 2-nitrotoluene with methanol to 2-methylaniline was successfully implemented. The transfer hydrogenation of 2-nitrotoluene with methanol showed much faster rate than its hydrogenation with hydrogen over X zeolites. Based on the reaction results over different modified X zeolites and activated carbon, a radical mechanism was proposed. @@@ [GRAPHICS] @@@ .

• 出版日期2016-1
• 单位同济大学