N-heterocyclic carbene complexes of Group 6 metals

作者：Wang Zhe; Jiang Lu; Mohamed Dara Khairunnisa Binte; Zhao Jin^*; Hor T S Andy

来源：Coordination Chemistry Reviews, 2015, 293: 292-326.

DOI：10.1016/j.ccr.2015.01.016

• N-heterocyclic carbene
• Complex
• Chromium
• Molybdenum
• Tungsten

Across the periodic table, Group 6 metals (Cr, Mo, W) play an important role in the development of carbene chemistry. In this review, we highlight the synthetic methodologies, structures, reactivities and functions of about 500 N-heterocyclic carbene (NHC) complexes of these metals reported in the last four decades. Some emerging trends and applications are also summarized.

• 出版日期2015-6-15