Noncrystalline blue-emitting 9,10-diphenylanthracene end-capped with triphenylamine-substituted fluorene

作者：Zhang, Yujian; Jin, Yanxian; Bai, Ru; Yu, Zhenwei; Hu, Bin; Ouyang, Mi^*; Sun, Jingwei; Yu, Chunhui; Liu, Junlei; Zhang, Cheng

来源：Journal of Photochemistry and Photobiology A: Chemistry , 2012, 227(1): 59-64.

DOI：10.1016/j.jphotochem.2011.11.003

• 9,10-Diphenylanthracene
• Hole-injection
• Blue-emitting material
• Thermal stability

Two blue-emitting oligomers, namely FDPA1 and FDPA2 containing 9,10-diphenylanthracene core end-capped with triphenylamine-substituted fluorene has been synthesized and characterized. The Spiro-configuration end-capping groups imparts two compounds with pronounced morphological stability (T-g > 185 degrees C, T-d > 420 degrees C) and excellent hole injection ability (E-HOMO > -5.27 eV) with the advantageous optical characteristics of corresponding core. Scanning electron microscope (SEM) and X-ray diffraction (XRD) reveal that the two oligomers form excellent amorphous films and possess good morphological stability after annealing.

• 出版日期2012-1-1
• 单位杭州电子科技大学; 台州学院; 浙江工业大学