科研之友
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摘要
A series of novel 1,3-alternate thiacalixarene derivatives containing triazole groups were synthesized directly from a conformationally mixed intermediate in high yields using click chemistry. They were used as building blocks for supramolecular self-assembly architecture, and shown to be good Ag+ receptors. As confirmed by AFM, one of the compounds was found to form nanorod aggregates by silver ion binding.
