A Donor-Acceptor Tetrathiafulvalene Ligand Complexed to Iron(II): Synthesis, Electrochemistry, and Spectroscopy of [Fe(phen)(2)(TTF-dppz)](PF6)(2)

作者：Dupont Nathalie; Ran Ying Fen; Liu Shi Xia^*; Grilj Jakob; Vauthey Eric; Decurtins Silvio; Hauser Andreas

来源：Inorganic Chemistry, 2013, 52(1): 306-312.

DOI：10.1021/ic3019277

The synthesis and photophysical properties of the complex [Fe(phen)(2)(TTF-dppz)](2+) (TTF-dppz = 4%26apos;,5%26apos;-bis-(propylthio)tetrathiafulvenyl[i]dipyrido[3,2-a:2%26apos;,3%26apos;-c]-phenazine, phen = 1,10-phenanthroline) are described. In this complex, excitation into the metal ligand charge transfer bands results in the population of a high-spin state of iron(II), with a decay lifetime of approximately 1.5 ns, in dichloromethane, at room temperature. An intraligand charge transfer state can also be obtained and has a lifetime of 38 ps. A mechanism for the different states reached is proposed based on transient absorption spectroscopy.

• 出版日期2013-1-7