Mechanical and thermal properties of epoxy-POSS reinforced(biphenyl diol formaldehyde/epoxy hybrid resin) composites

作者：Chen Shihui; Gao Jungang^*; Han Hongzhe; Wang Chao

来源：Iranian Polymer Journal, 2014, 23(8): 609-617.

DOI：10.1007/s13726-014-0255-6

• Epoxy resin
• Biphenyldiol formaldehyde resin
• Polyhedral oligomeric silsesquioxane
• Mechanical property
• Thermal degradation kinetics

To enhance the properties of epoxy composites, the biphenyl diol formaldehyde resin (BPFR) and glycidyloxypropyl polyhedral oligomeric silsesquioxane (G-POSS) were synthesized and used for modification of fiberglass reinforced composites of epoxy resin (ER). The BPFR was employed to cure epoxy resin with different G-POSS contents and the laminates of fiber-glass reinforced hybrid composites prepared from BPFR, ER and G-POSS. The dynamic mechanical properties, thermal properties, mechanical and electrical properties of the hybrid composites were characterized by dynamic mechanical analyzer, thermogravimetric analyzer and electroproperty detector. The results showed that the T-g of the composites is increased with the addition of G-POSS. When the content of G-POSS is 5 wt%, the tensile and impact strength of the hybrid composites are 249.87 MPa and 63.83 kJ/m(2), respectively, which are all 30 % higher than those of non-added composites. At G-POSS content of 7 wt%, T-g of the material is 9.6 degrees C higher than pure BPFR/ER composite, and the initial decomposition temperature, T-id, is enhanced by about 29 degrees C. Dielectric constant, e, and dielectric loss, tan delta, of the hybrid composites are between 0.53-0.7 and between 0.004-0.012, respectively.

• 出版日期2014-8
• 单位河北大学