Direct electron transfer of bilirubin oxidase (Myrothecium verrucaria) at an unmodified nanoporous gold biocathode

作者:Salaj Kosla Urszula; Poeller Sascha; Beyl Yvonne; Scanlon Micheal D; Beloshapkin Sergey; Shleev Sergey; Schuhmann Wolfgang*; Magner Edmond
来源:Electrochemistry Communications, 2012, 16(1): 92-95.
DOI:10.1016/j.elecom.2011.12.007

摘要

Well defined mediatorless bioelectrocatalytic reduction of oxygen with high current densities of 0.8 mA cm(-2) was obtained on nanoporous gold electrodes modified with Myrothecium verrucaria bilirubin oxidase. A stable faradaic response was observed when the enzyme modified electrode was coated with a specifically designed electrodeposition polymer layer. The response of the enzyme electrode was only slightly inhibited by the addition of F-.

  • 出版日期2012-3