A (3,12)-connected coordination network based on rare tetragonal prism-like Zn-8(II) cluster

作者：Liu, Zhong-Yi; Yang, En-Cui^*; Zhao, Xiao-Jun^*

来源：Inorganic Chemistry Communications, 2016, 70: 197-200.

DOI：10.1016/j.inoche.2016.06.016

• Hydrothermal reaction
• Tetragonal prism cluster
• Triazole
• Luminescent

Hydrothermal reaction of zinc oxide, 1,2-benzenedicarboxylic acid (H(2)pa) and 1,2,4-triazole (Htrz) yielded a (3,12)-connected 2-D coordination network [Zn-8(trz)(4)(OH)(4)(pa)(4)](n), (1), in which rare tetragonal prism-like Zn-8(II) clusters and tridentate 1,2-benzenedicarboxylate act as 12- and 3-connected nodes, respectively. Moreover, the luminescent emission spectra and thermostability of 1 have been investigated.

• 出版日期2016-8
• 单位天津师范大学