Hydrothermal Synthesis and Crystal Structure of A One-dimensional Zigzag Chain Based on 2,4 '-Biphenyl-dicarboxylic Acid and 4,4 '-Bipyridine

作者：Wang Aidong^*; Li Wenbo; Guo Feng; Zhang Xiuling

来源：Asian Journal of Chemistry, 2010, 22(9): 7426-7428.

• Hydrothermal Synthesis
• Crystal structure
• One-dimensional
• 2,4 '-Biphenyl-dicarboxylic acid
• 4,4 '-Bipyridine

Co-crystallization of 2,4'-biphenyl-dicarboxylic acid (2, 4'-dpa) and 4,4'-bipyridine (4,4'-bpy) was synthesized and characterized by X-ray diffraction at the orthorhombic, space group Pbca with a = 24.421(5), b = 9.055(10), c = 17.843(2) angstrom, alpha = beta = gamma = 90 degrees, Mr = 398.40, V = 3945.4(7) angstrom(3), D(c) = 1.341 g/cm(3), F(000) = 1664 and Z = 8. There are one molecule of 2,4'-biphenyl-dicarboxylic acid and 4,4'-bipyridine in the asymmetric unit. The dihedral angle between the pyridine ring planes is 2.40 degrees. The intermolecular hydrogen bonds are observed in the compound.

• 出版日期2010-10
• 单位黄山学院