Axially Engineered Metal-Insulator Phase Transition by Graded Doping VO2 Nanowires

作者：Lee Sangwook; Cheng Chun; Guo Hua; Hippalgaonkar Kedar; Wang Kevin; Suh Joonki; Liu Kai; Wu Junqiao^*

来源：Journal of the American Chemical Society, 2013, 135(12): 4850-4855.

DOI：10.1021/ja400658u

The abrupt first-order metal-insulator phase transition in single-crystal vanadium dioxide nanowires (NWs) is engineered to be a gradual transition by axially grading the doping level of tungsten. We also demonstrate the potential of these NWs for thermal sensing and actuation applications. At room temperature, the graded-doped NWs show metal phase on the tips and insulator phase near the center of the NW, and the metal phase grows progressively toward the center when the temperature rises. As such, each individual NW acts as a microthermometer that can be simply read out with an optical microscope. The NW resistance decreases gradually with the temperature rise, eventually reaching 2 orders of magnitude drop, in stark contrast to the abrupt resistance change in undoped VO2 wires. This novel phase transition yields an extremely high temperature coefficient of resistivity similar to 10%/K, simultaneously with a very low resistivity down to 0.001 Omega.cm, making these NWs promising infrared sensing materials for uncooled microbolometers. Lastly, they form bimorph thermal actuators that bend with an unusually high curvature, similar to 900 m(-1).K-1 over a wide temperature range (35-80 degrees C), significantly broadening the response temperature range of previous VO2 bimorph actuators. Given that the phase transition responds to a diverse range of stimuli-heat, electric current, strain, focused light, and electric field-the graded-doped NWs may find wide applications in thermo-opto-electro-mechanical sensing and energy conversion.

• 出版日期2013-3-27