Aquabis(o-phenylenediamine-kappa(2) N,N ')(o-phenylenediamine-kappa N)zinc(II) bis(p-toluenesulfonate) trihydrate

作者:Qian Bao Hua*; Ma Wei Xing; Lu Lu De; Yang Xu Jie; Wang Xin
来源:Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M2930-U673.
DOI:10.1107/S1600536807052075

摘要

In the title compound, [Zn(C6H8N2)(3)(H2O)](C7H7SO3)(2)center dot-3H(2)O, the Zn atom has a slightly tetragonally distorted octahedral geometry, with four shorter equatorial Zn-N and Zn-O bonds [2.153 (4)-2.189 (3) angstrom] and two longer axial Zn-N bonds [2.239 (4) and 2.243 (4) angstrom]. The crystal packing is stabilized by weak intermolecular N-H center dot center dot center dot O hydrogen bonds.

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