Miscibility and Thermal Behavior of Pullulan/Polyacrylamide Blends

作者：Bhat Vishwanath; Shivakumar H R^*; Sheshappa Rai K; Ganesh Sanjeev; Prasad P; Guru G S; Bhavya B B

来源：Journal of Macromolecular Science Part A-Pure and Applied Chemistry, 2011, 48(11): 920-926.

DOI：10.1080/10601325.2011.614864

• Blends
• miscibility
• viscosity
• Pullulan
• glass transition

Blends of Pullulan (PU) and Polyacrylamide (PAM) having biomedical applications were prepared and characterized in order to evaluate the miscibility of natural component with the synthetic one. Blends with different composition ratios were prepared using water as common solvent. Viscosity, ultrasonic velocity and density were measured at 30 and 40 degrees C. Furthermore, the blend films were prepared by a solution casting method and analyzed by DSC, FTIR and TGA methods. Results of ultrasonic and density methods revealed the semi-miscibility of the blend. Using viscosity data, interaction parameters (Chee's 'mu' and Sun's 'alpha') were computed. The values confirmed that the blend is miscible when the Pullulan content is less than 20% in the blend. Change in temperature had no effect on the miscibility nature of the blends. Intermolecular interactions of hydrogen bonding type were confirmed by DSC and FTIR methods. Thermal behavior of blends was investigated using TGA method.

• 出版日期2011