A chiral three-dimensional network in poly[mu-4,4'-bipyridine-di-mu-formato-cadmium(II)]

作者：Zhao Li; Lin Jian Li; Xu Wei; Xie Hong Zhen^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2009, 65(4): M433-U815.

DOI：10.1107/S1600536809009969

In the title compound, [Cd(HCOO)(2)(C(10)H(8)N(2))]n, the Cd(II) ion, located on a position with 2.22 site symmetry, is surrounded by two 4,4'-bipyridine ligands and four formate ligands in a distorted octahedral CdN(2)O(4) coordination. The 4,4'-bipyridine ligands bridge the metal ions, forming one-dimensional chains along different directions, which are further connected by formate ligands into a topologically (10(10).12(4).14)(10)(3) three-dimensional network.

• 出版日期2009-4
• 单位宁波大学