A four-state kinetic model for the carrier-induced degradation in multicrystalline silicon: Introducing the reservoir state

作者：Fung Tsun Hang^*; Kim Moonyong; Chen Daniel; Chan Catherine E; Hallam Brett J; Chen Ran; Payne David N R; Ciesla Alison; Wenham Stuart R; Abbott Malcolm D

来源：Solar Energy Materials and Solar Cells, 2018, 184: 48-56.

DOI：10.1016/j.solmat.2018.04.024

• Multicrystalline silicon
• Carrier induced degradation
• Kinetic state model
• Defect reservoir
• Hydrogen: Anneal

In this work, we present new insight into the multi-crystalline silicon carrier-induced defect (CID) by performing multiple degradation and regeneration cycles and further investigation on the partial recovery of me-CID through extended dark annealing (DA). The maximum normalised defect density was found to decay exponentially with the number of cycles, suggesting that the defect precursors were slowly depleted by DA. A four state kinetic model is proposed by introducing a reservoir state. Simulation results generated by mathematical modelling based on the proposed state diagrams exhibited good agreement with the experimental results. Extended DA on a partially recovered sample combined with simulation results suggests that the capability of defect formation through DA and the existence of the reservoir state proposed herein were the root causes for the partial recovery reported in the literature. Finally, the change in bound hydrogen state is speculated to cause the modulation of me-CID formation. A qualitative reservoir model based on the interaction between hydrogen molecules (H-2), boron-hydrogen pairs (B-H) and free hydrogen (H+, H-o) is proposed and further discussed.

• 出版日期2018-9