A new hybrid Keggin-type molybdophosphate: (H(2)phen)[Cu(phen)(2)][PMo12O40]

作者：Li Ming Xue; Yu Li; Bi Dong Qin; Wang Jing Ping^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2006, 62: M2570-M2572.

DOI：10.1107/S1600536806036506

An organic-inorganic hybrid compound constructed from a Keggin-type molybdophosphate polyoxoanion, a Cu-I coordination cation and a protonated 1,10-phenanthroline subunit, namely 1,10-phenanthrolinium bis(1,10-phenanthroline)copper(I) dodecamolybdophosphate, (C12H10N2)-[Cu(C12H8N2)(2)][PMo12O40] or (H(2)phen)[Cu(phen)(2)]-[PMo12O40], has been prepared under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction. The polyoxoanion is constructed from a central PO4 tetrahedron which shares its O atoms with four {Mo3O16} trinuclear groups, each of which is made up of three edge-sharing {MoO6} octahedra. In the [Cu(phen)(2)](+) countercation, the Cu atom is coordinated by four N atoms from two 1,10-phenanthroline ligands.

• 出版日期2006-10
• 单位河南大学