A high yielding, one-pot synthesis of dialkyl carbonates from alcohols using Mitsunobu's reagent

作者：Chaturvedi Devdutt^*; Mishra Nisha; Mishra Virendra

来源：Tetrahedron Letters, 2007, 48(29): 5043-5045.

DOI：10.1016/j.tetlet.2007.05.103

• Mitsunobu's reagent
• carbon dioxide
• alcohols
• dialkylcarbonates
• carbonation

A Mitsunobu-based protocol has been developed for the synthesis of symmetrical and unsymmetrical dialkylcarbonates from a variety of primary, secondary and tertiary alcohols using gaseous carbon dioxide, in good to excellent yields. This protocol is mild and efficient compared to other reported methods.

• 出版日期2007-7-16