A novel two-fold interpenetrating 3D metal-organic framework based on Lindqvist-type hexamolybdate: Synthesis, structure, electrochemical and photocatalytic properties

作者：Wang, Xiuli^*; Zhang, Huixiu; Wang, Xiang; Zhang, Shan; Liu, Jiahuan; Lin, Hongyan; Liu, Guocheng

来源：Inorganic Chemistry Communications, 2018, 88: 60-64.

DOI：10.1016/j.inoche.2017.12.015

• Polyoxometalate
• Hexamolybdate
• Interpenetrating framework
• Photocatalytic activity

A novel Lindqvist-type hexamolybdate-based metal-organic framework (MOF), [CuL2(Mo6O19)] (L = 4,4'-bis(1H-benzotriazoloxymethyl)biphenyl) (1), has been synthesized solvothermally. In compound 1, the L ligands connect Cu(II) atoms to form a 2D grid network, and [Mo6O19](2-) polyoxoanions act as pillars connecting the layers into a 3D MOF. Such two MOFs interpenetrate each other to give a "3D + 3D" two-fold interpenetrating framework. The title complex represents the first example based on L ligand. The electrochemical property of 1 and its photocatalytic activity for the degradation of organic dyes have also been investigated.

• 出版日期2018-2
• 单位渤海大学