An all-inorganic polyoxometalate-polyoxocation chemical garden

作者:Points Laurie J; Cooper Geoffrey J T; Dolbecq Anne; Mialane Pierre; Cronin Leroy*
来源:Chemical Communications, 2016, 52(9): 1911-1914.
DOI:10.1039/c5cc09536k

摘要

Herein, we show it is possible to produce wholly inorganic chemical gardens from a cationic polyoxometalate (POM) seed in an anionic POM solution, demonstrating a wholly POM-based chemical garden system that produces architectures over a wide concentration range. Six concentration dependent growth regimes have been discovered and characterized: clouds, membranes, slugs, tubes, jetting and budding.

  • 出版日期2016