A well-defined NHC-Ir(III) catalyst for the silylation of aromatic C-H bonds: substrate survey and mechanistic insights

作者:Rubio Perez Laura; Iglesias Manuel; Munarriz Julen; Polo Victor; Passarelli Vincenzo; Perez Torrente Jesus J; Oro Luis A
来源:Chemical Science, 2017, 8(7): 4811-4822.
DOI:10.1039/c6sc04899d

摘要

A well-defined NHC-Ir(iii) catalyst provides access to a wide range of aryl- and heteroarylsilanes by intermolecular dehydrogenative C–H bond silylation.

  • 出版日期2017-7