3,6-Disubstituted carbazole chromophores containing thiazole and benzothiazole units: Synthesis, characterization and first-order hyperpolarizabilities

作者：Ying Qian^*

来源：Dyes and Pigments, 2008, 76(1): 277-281.

DOI：10.1016/j.dyepig.2006.08.040

• nonlinear optical chromophores
• the first-order hyperpolarizabilities
• heteroaromatic compounds

3,6-Disubstituted carbazole chromophores containing thiazole and benzothiazole units were synthesized and characterized by NMR, IR, and UV. The first-order hyperpolarizabilities (0) were calculated via solvatochromic method. Our experiments suggest that the incorporation of thiazole and benzothiazole into carbazole-based chromophores can allow for significant enhancement of molecular hyperpolarizabilities. Nonlinear optical properties of A pi rD pi A carbazole chromophores are superior to those of the corresponding D pi A aryl compounds.

• 出版日期2008
• 单位东南大学