A highly selective diarylethene-based fluorescent sensor for respective recognition of Zn2+ and F-

作者：Liu, Jingjing; Liu, Hongliang^*; Pu, Shouzhi^*

来源：Journal of Photochemistry and Photobiology A: Chemistry , 2016, 324: 14-22.

DOI：10.1016/j.jphotochem.2016.03.011

• Photochromism
• Diarylethenes
• 8-methoxyquinoline unit
• Fluorescent sensor
• Zn2+
• F-

A new photochromic diarylethene with an acetohydrazino-linked 8-methoxyquinoline unit was synthesized and its structure was determined by single crystal X-ray diffraction analysis. The diarylethene exhibited favorable photochromism and fluorescent switching properties by photo irradiation. Especially, it can sever as a highly selective fluorescent sensor for recognition of Zn2+ and F- ions, respectively. When triggered by Zn2+, its fluorescence intensity was enhanced evidently and its emission peak was red-shifted from 418 nm to 469 nm with a concomitant color change from dark to bright blue. On the other hand, F- can induce its emission peak to redshift by 129 nm with an emission intensity of 13-fold at the plateau under the same conditions.

• 出版日期2016-6-30
• 单位江西科技师范大学