Bi-based lead-free ceramic multilayer actuators using AgPd-(Na0.51K0.47Li0.02)(Nb0.8Ta0.2)O-3 composite inner electrodes

作者：Van Quyet Nguyen; Kang Jin Kyu; Han Hyoung Su; Lee Hyun Young; Jeong Soon Jong; Ahn Chang Won; Kim Ill Won; Lee Jae Shin^*

来源：Sensors and Actuators A: Physical , 2013, 200: 107-113.

DOI：10.1016/j.sna.2012.10.036

• Multilayer actuator
• Lead-free ceramics
• Internal electrode
• Thermal shrinkage
• Electric field-induced strain

We investigated the effect of inner electrode composition on the microstructure and electromechanical properties of Bi-0.5(Na0.82K0.18)(0.5)TiO3 (BNKT) multilayer ceramic actuators. Using tape-casting and screen printing techniques, multilayered laminates were prepared by stacking green sheets of Nb-modified BNKT ceramic layers with AgPd (70/30 in weight ratio) thick films as the inner electrode. After co-firing at temperatures of 1100-1140 degrees C for 4 h in air, the multilayered structure revealed significant camber as well as cracks due to the mismatch in thermal shrinkage between the ceramic and the AgPd layer. However, the addition of 10 wa% (K0.47Na0.51Li0.02)(Nb0.8Ta0.2)O-3 (KNLNT) powder into the inner electrode markedly suppressed the generation of co-firing-induced defects. More surprisingly, the normalized electric-field induced strain (S-max/E-max) of BNKT multilayer actuators was enhanced from 110 pm/V to 350 pm/V by adding ceramic KNLNT into the AgPd inner electrode.

• 出版日期2013-10-1