A 2-D coordination polymer with (Cu4S4)-S-I-core as joints

作者：Zhu Hai Bin; Xu Gang; Ji Jun Feng; Gou Shao Hua^*

来源：Journal of Coordination Chemistry, 2009, 62(14): 2276-2282.

DOI：10.1080/00958970902838784

• Copper(I)
• Multinuclear cluster
• NS-donor
• Crystal structure

A coordination polymer based on copper(I) and a heterocyclic thione ligand, HPPT4 (HPPT4 = 4-pyridin-4-yl-pyrimidine-2-thiol) has been prepared. The compound C21H19Cu2N7OS2 (1) has a 2-D polymeric structure with [image omitted]-core as joints linked by -thiolate bridges. Crystal data for compound 1: Monoclinic, space group C2/c, a = 22.346(14) , b = 15.649(10) , c = 13.588(9) , = 97.183(12), V = 4714(5) 3, and Z = 8. Compound 1 displays multiple emissions with maximum wavelength at 391 and 469 nm under photoexcitation at 340 nm.

• 出版日期2009
• 单位东南大学