Potentiometric cross-sensitive PD sensors for the simultaneous determination of nicotinic acid and pyridoxine hydrochloride in aqueous solutions

作者：Bobreshova O V^*; Parshina A V; Pozhidaeva Yu V

来源：Journal of Analytical Chemistry, 2013, 68(4): 321-327.

DOI：10.1134/S1061934813020044

• Donnan potential
• cross-sensitive sensors
• multisensory system
• chemometrics
• multidimensional analytical methods
• perfluorinated sulfo cation-exchanger polymer
• nicotinic acid
• pyridoxine hydrochloride

A potentiometric multisensory system is developed for the rapid simultaneous determination of pyridoxine hydrochloride and nicotinic acid in aqueous solutions. Sensors for which analytical signal is constructed by the Donnan potential are used within a multisensory system as cross-sensitive elements. In solutions containing both components in concentrations from 1.0 x 10(-4) to 1.0 x 10(-2) M, the relative error of analysis did not exceed 10%. Standard titrimetry and spectrophotometry methods were used for the reference analysis of the target vitamins in multicomponent solutions.

• 出版日期2013-4