A new 1-D extended vanadoborate containing triply bridged metal complex units

作者：Zhou, Jian^*; Liu, Xing; Hu, Feilong; Zou, Huahong; Li, Xiaojuan

来源：Inorganic Chemistry Communications, 2012, 25: 51-54.

DOI：10.1016/j.inoche.2012.07.050

• Hydrothermal synthesis
• Polyoxovanadium
• Borate
• Crystal structures

A new 1-D vanadoborate {[Na(H2O)(4)](3)[V12B18O54(OH)(6)(H2O)](2)}(H(4)tren)(4)center dot(H3O)center dot 41H(2)O (1, tren = tris(2-aminoethyl)amine) has been hydrothermally synthesized and structurally characterized. 1 consists of 1-D polymeric anions {[Na(H2O)(4)](3)[V12B18O54(OH)(6)(H2O)](2)(17-)}(n), protonated H(4)tren(4+), H3O+ ions and free H2O molecules. The [V12B18O54(OH)(6)(H2O)](10-) clusters (denoted on V12B18) are connected by three complex [Na(H2O)(4)](+) ions as bridges into 1-D chain. 1 is the only example of triply bridged vanadoborate units by three metal complex units. The magnetic susceptibility shows the antiferromagnetic interaction between V-IV cations in 1.

• 出版日期2012-11
• 单位广西师范大学; 重庆师范大学; 玉林师范学院