Organic multishell isostructural host-guest crystals: fullerenes C-60 inside a nitroxide open framework

作者:Bardelang David*; Giorgi Michel; Pardanaud Cedric; Hornebecq Virginie; Rizzato Egon; Tordo Paul; Ouari Olivier
来源:Chemical communications, 2013, 49(34): 3519-3521.
DOI:10.1039/c3cc00170a

摘要

The dinitroxide biradical bTbk crystallizes forming hexagonal open frameworks with one-dimensional corrugated channels filled with crystallization solvent. The large pockets constitutive of the channels allowed the inclusion of C-60 in the paramagnetic network. The rapidity and high fidelity of crystal growth were used to prepare isostructural multilayer host-guest crystals successively stained with C-60.

  • 出版日期2013