A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF) ((HBu6L)-Bu-t)] center dot 3DMF ([(H6Bu6L)-Bu-t]Cl = tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)

作者：Wu, Si-Meng; Chen, Xin; Xin, Zhifeng; Jia, Ai-Quan; Zhang, Qian-Feng^*

来源：Zeitschrift Fur Naturforschung Section B-a Journal of Chemical Sciences, 2018, 73(5): 323-327.

DOI：10.1515/znb-2018-0044

• crystal structure
• molybdenum(VI)
• synthesis
• triaminoguanidine

Interaction of (NH4)(6)Mo7O24 center dot 4H(2)O with tris-(3,5-di-tert-butyl-2-hydroxy-benzylidene) triaminoguanidinium chloride [(H6Bu6L)-Bu-t]Cl in DMF-H2O resulted in isolation of a neutral dinuclear Mo(VI) complex [Mo2O4 (OH2)(DMF) ((HBu6L)-Bu-t)] center dot 3DMF. The C-3-symmetric-type ligand (HBu6L)-Bu-t is coordinated to two cis-{MoO2}(2+) moieties via phenolic-oxygen, guanidine nitrogen and azomethine nitrogen atoms, and the remaining sixth coordination sites of the molybdenum centers are occupied by the oxygen atoms from the solvent molecules.

• 出版日期2018-5
• 单位安徽工业大学