Stepwise post-modification immobilization of palladium Schiff-base complex on to the OMS-Cu (BDC) metal-organic framework for Mizoroki-Heck cross-coupling reaction

作者：Alamgholiloo, Hassan; Rostamnia, Sadegh^*; Hassankhani, Asadollah; Khalafy, Jabbar; Baradarani, Mehdi M.; Mahmoudi, Ghodrat; Liu, Xiao^*

来源：Applied Organometallic Chemistry, 2018, 32(11): e4539.

DOI：10.1002/aoc.4539

• metal organic frameworks
• Mizoroki-Heck reaction
• open metal site MOF
• Pd-II@Cu (BDC)
• 2-Py-SI

Palladium ions were successfully immobilized within the pores of open metal site (OMS) metal organic frameworks (MOFs) with Schiff-base (2-Py-SI) grafted in OMS-Cu (BDC) using the hydrothermal method. This Schiff-base complex on the Cu (BDC) greatly increased catalytic activity and acted as an efficient stabilizer of Pd ions. The hydrothermal method was a more efficient method for generating small metal ions in the MOF structures. The results revealed that the Pd-II@Cu (BDC)/2-Py-SI is a promising catalyst for the Mizoroki-Heck coupling reaction. The proposed catalyst has better recyclability and can be reused several times without apparent loss of activity.

• 出版日期2018-11
• 单位华中师范大学