GREEN CHEMICAL TOOLS IN ORGANOPHOSPHORUS CHEMISTRY-ORGANOPHOSPHORUS TOOLS IN GREEN CHEMISTRY

作者：Keglevich Gyoergy^*; Gruen Alajos; Balint Erika; Kiss Nora Zs; Kovacs Rita; Molnar Istvan G; Blastik Zsofia; Toth R Viola; Fehervari Andras; Csontos Istvan

来源：Phosphorus, Sulfur, and Silicon and the Related Elements, 2011, 186(4): 613-620.

DOI：10.1080/10426507.2010.507725

• Green chemistry
• in situ Fourier transform IR spectroscopy
• MW-assisted organic synthesis
• organophosphorus chemistry
• phase transfer catalysis
• Pt(II)-P(III) complexes

A variety of reactions including esterifications, alkylations, additions, cycloadditions, fragmentations, and condensations were carried out under microwave MW-assisted and solventless conditions, occasionally in ionic liquids (ILs). In a few cases, MW was synergic with phase transfer catalysis or could substitute it. A variety of P(III) ligands were developed and converted to Pt(II) complexes that can be used as catalysts. Finally, phosphorylations and the Kabachnik-Fields reaction were monitored and optimized by an on-line method, in situ Fourier transform IR spectroscopy.

• 出版日期2011