A Novel Alkylated Indacenodithieno[3,2-b]thiophene-Based Polymer for High-Performance Field-Effect Transistors

作者：Zhang, Weimin; Han, Yang; Zhu, Xiuxiu; Fei, Zhuping^*; Feng, Yu; Treat, Neil D.; Faber, Hendrik; Stingelin, Natalie; McCulloch, Iain; Anthopoulos, Thomas D.; Heeney, Martin^*

来源：Advanced Materials, 2016, 28(20): 3922-+.

DOI：10.1002/adma.201504092

• HIGH-MOBILITY
• SEMICONDUCTING POLYMERS
• CONJUGATED POLYMERS
• CHARGE-TRANSPORT
• SOLAR-CELLS
• PHOTOVOLTAIC PROPERTIES
• ELECTRON MOBILITIES
• AMORPHOUS-SILICON
• HIGH HOLE
• COPOLYMER

A novel rigid donor monomer, indacenodithieno[3,2-b]thiophene (IDTT), containing linear alkyl chains, is reported. Its copolymer with benzothiadiazole is an excellent p-type semiconductor, affording a mobility of 6.6 cm(2) V-1 s(-1) in top-gated field-effect transistors with pentafluorobenzenethiol-modified Au electrodes. Electrode treatment with solution-deposited copper(I) thiocyanate (CuSCN) has a beneficial hole-injection/electron-blocking effect, further enhancing the mobility to 8.7 cm(2) V-1 s(-1).

• 出版日期2016-5-25
• 单位广西民族大学