Mobilizing Cu(I) for Carbon-Carbon Bond Forming Catalysis in the Presence of Thiolate. Chemical Mimicking of Metallothioneins

作者：Zhang Zhihui; Lindale Matthew G; Liebeskind Lanny S^*

来源：Journal of the American Chemical Society, 2011, 133(16): 6403-6410.

DOI：10.1021/ja200792m

Copper(I) is rendered catalytically viable in the presence of thiolate by the design of a small molecule chemical analogue of the metallothionein system in which an N-O reactant serves the same conceptual purpose of the S-S reactant of the biological system.

• 出版日期2011-4-27