New pregaliellalactonoids from Galiella rufa

作者:Escobar Zilma; Williams Headley; Phipps Richard; Karunakaran Deepa; Steele Jonathan; Sterner Olov*
来源:Phytochemistry Letters, 2015, 12: 138-141.
DOI:10.1016/j.phytol.2015.03.009

摘要

An extract of a culture of the fungus Galiella rufa yielded several new derivatives of pregaliellalactone (1) that were characterised by NMR and MS experiments. The tetraene 4 has been reported previously, but was in this investigation isolated in sufficient amounts for the determination of the configuration of the C-4/C-5 double bond which is Z, not E. The possibility that any of the new compounds are involved in the biosynthesis of 1 is discussed.

  • 出版日期2015-6