科研之友
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摘要
Biodiesel has been synthesized from karanja, mahua and hybrid (karanja and mahua (50:50 v/v)) feedstocks. A high yield in the range of 95-97% was obtained with all the three feedstocks. Conversion of vegetable oil to fatty acid methyl esters was found to be 98.6%, 95.71% and 94% for karanja, mahua and hybrid feedstocks respectively. The optimized reaction parameters were found to be 6:1 (methanol to oil) molar ratio, H(2)SO(4) (1.5% v/v), at 55 +/- 0.5 degrees C for 1 h during acid esterification for the three feedstocks. During alkaline transesterification, a molar ratio of 8:1 (methanol to oil), 0.8 wt.% KOH (wt/wt) at 55 +/- 0.5 degrees C for 1 h was found to be optimum to achieve high yield for karanja oil. For mahua oil and the hybrid feedstock, 6:1 (methanol to oil) molar ratio, 0.75 (w/w) KOH at 55 +/- 0.5 degrees C for 1 h was optimum for alkaline transesterification to obtain a high yield. High yield and conversion from hybrid feedstock during transesterification reaction was an indication that the reaction was not selective for any particular oil. (1)H NMR has been used for the determination of conversion of the feedstock to biodiesel.
- 出版日期2010-10
