MECHANISTIC INVESTIGATION OF OXIDATION OF SOME AMINO ACIDS BY BIS(DIHYDROGEN TELLURATE)ARGENTATE(III) ION IN ALKALINE MEDIUM. A KINETIC STUDY

作者：Huo Shuying^*; Song Changying; Shan Jinhuan; Shen Shigang; Sun Hanwen

来源：Journal of the Chilean Chemical Society, 2009, 54(4): 385-390.

DOI：10.4067/s0717-97072009000400013

• Bis(dihydrogen tellurate)argentate(III)
• amino acid
• Kinetics and mechanism
• Redox reactions

The oxidation of leucine, isoleucine and valine by bis(dihydrogen tellurate)argentate(III) ion was studied by stopped-flow technique. It was both first order with respect to Ag(III) complex and amino acids. A plausible mechanism was proposed form the kinetics study. And the rate equations derived from mechanism can explain all experimental phenomena. The activation parameters along with the second order rate constants were calculated.

• 出版日期2009-12
• 单位河北大学