Novel polymer coupling chemistry based upon latent cysteine-like residues and thiazolidine chemistry

作者:Carlson Joseph S; Hill Megan R; Young Taiga; Costanzo Philip J*
来源:Polymer Chemistry, 2010, 1(9): 1423-1426.
DOI:10.1039/c0py00191k

摘要

Chain end functional polymers were prepared via reversible addition-fragmentation transfer (RAFT) polymerization techniques that were further chain extended with acrylonitrile. Under reducing conditions, latent cysteine-like residues were exposed at the chain ends. A variety of reduction conditions were explored and base polymers were then tethered together via thiazolidine chemistry.

  • 出版日期2010