A thermally robust di-n-butyl thorium complex with an unstable dimethyl analogue

作者:Cruz Carlos A; Emslie David J H*; Jenkins Hilary A; Britten James F
来源:Dalton Transactions, 2010, 39(29): 6626-6628.
DOI:10.1039/c002122a

摘要

Methyl and n-butyl thorium complexes of a rigid 2,6-bis(anilidomethyl)pyridine ligand have been prepared; the n-butyl complex is thermally stable, even at 60 degrees C, while the methyl complexes exhibit a high tendency to eliminate methane via sigma-bond metathesis.

  • 出版日期2010