Uniform second Li ion intercalation in solid state epsilon-LiVOPO4

作者：Wangoh Linda W; Sallis Shawn; Wiaderek Kamila M; Lin Yuh Chieh; Wen Bohua; Quackenbush Nicholas F; Chernova Natasha A; Guo Jinghua; Ma Lu; Wu Tianpin; Lee Tien Lin; Schlueter Christoph; Ong Shyue Ping; Chapman Karena W; Whittingham M Stanley; Piper Louis F J^*

来源：Applied Physics Letters, 2016, 109(5): 053904.

DOI：10.1063/1.4960452

Full, reversible intercalation of two Li+ has not yet been achieved in promising VOPO4 electrodes. A pronounced Li+ gradient has been reported in the low voltage window (i.e., second lithium reaction) that is thought to originate from disrupted kinetics in the high voltage regime (i.e., first lithium reaction). Here, we employ a combination of hard and soft x-ray photoelectron and absorption spectroscopy techniques to depth profile solid state synthesized LiVOPO4 cycled within the low voltage window only. Analysis of the vanadium environment revealed no evidence of a Li+ gradient, which combined with almost full theoretical capacity confirms that disrupted kinetics in the high voltage window are responsible for hindering full two lithium insertion. Furthermore, we argue that the uniform Li+ intercalation is a prerequisite for the formation of intermediate phases Li1.50VOPO4 and Li1.75VOPO4. The evolution from LiVOPO4 to Li2VOPO4 via the intermediate phases is confirmed by direct comparison between O K-edge absorption spectroscopy and density functional theory. Published by AIP Publishing.

• 出版日期2016-8-1