A polyhedral oligomeric silsesquioxane functionalized copper trimesate

作者:Sanil E S; Cho Kyung Ho; Hong Do Young; Lee Ji Sun; Lee Su Kyung; Ryu Sam Gon; Lee Hae Wan; Chang Jong San; Hwang Young Kyu*
来源:Chemical Communications, 2015, 51(40): 8418-8420.
DOI:10.1039/c5cc01928a

摘要

A metal-organic framework (MOF), copper trimesate (Cu-3(BTC)(2)), was selectively functionalized with aminopropylisooctyl polyhedral oligomeric silsesquioxane (O-POSS) to make the external surface of Cu-3(BTC)(2) hydrophobic and thereby enhance the stability of the material against humidity. POSS modification was also successfully applied to other MOFs such as MOF-74 and MIL-100.

  • 出版日期2015