A Direct Methanol Alkaline Fuel Cell Based on Poly(phenylene) Anion Exchange Membranes

作者：Janarthanan Rajeswari^*; Pilli Satyananda Kishore; Horan James L; Gamarra Daniel A; Hibbs Michael R; Herring Andrew M

来源：Journal of the Electrochemical Society, 2014, 161(9): F944-F950.

DOI：10.1149/2.1041409jes

The Investigation of the performance of poly(phenylene) based anion exchange membranes (AEMs) in a direct methanol fuel cell is reported. The fuel cell performances were tested with different anode gas diffusion layers as a function of concentrations of fuel and electrolyte using two commercially available platinum catalysts supported on carbon. Normalized current density values demonstrated good performance for a poly(phenylene) AEM, with a cation consisting of six methylene spacers attached to a trimethyl ammonium group, with a maximum current density of 11.8 mA cm(-2) mg(-1) in a KOH free fuel. The platinum catalyst (46%) from Tanaka showed a better performance (10.4 mA cm(-2) mg(-1)) compared to the platinum catalyst from E-TEK (5.1 mA cm(-2) mg(-1)) in 1M methanol fuel feed under identical conditions. We observed that the MEA with a Zoltek gas diffusion layer on the anode showed the best performance (226 mA cm(-2) and 53.8 mW cm(-2)) in the presence of KOH, suggesting that a hydrophilic gas diffusion layer plays a significant role in improving the fuel cell performance. A durability test for a MEA in 1M methanol and 1M KOH for 67 h showed an overall degradation rate of 400 mu V h(-1).

• 出版日期2014