A novel 3D 4-(1H-1,2,4-triazol-1-ylmethyl)benzoate cadmium coordination polymer

作者：Ding, Ruiqiang; Yan, Pengfei^*; Hou, Guangfeng; Chen, Peng; Wang, Yan; Li, Guangming

来源：Synthetic Metals, 2012, 162(21-22): 1894-1897.

DOI：10.1016/j.synthmet.2012.07.024

• Crystal structure
• 4-(1H-1,2,4-triazol-1-ylmethyl)benzoic acid
• Cadmium
• Coordination polymer
• Luminescence

A novel coordination polymer [Cd(4-tzbc)(2)](n) (1) [H(4-tzbc) = 4-(1H-1,2,4-triazol-1-ylmethyl)benzoic acid] has been isolated by direct combination of unsymmetrical semi-rigid 4-tzbc with cadmium nitrate by the solvothermal method. Single-crystal X-ray diffraction study reveals that complex 1 exhibits a novel 3D rutile type framework with 1D channel. Thermal analysis suggests that 1 is of high thermostability at 345 degrees C. The photoluminescence of complex 1 reveals a cadmium ion disturbed ligand emission.

• 出版日期2012-12
• 单位黑龙江大学