Deciphering DNA-based asymmetric catalysis through intramolecular Friedel-Crafts alkylations

作者：Park Soyoung; Ikehata Keiichi; Watabe Ryo; Hidaka Yuta; Rajendran Arivazhagan; Sugiyama Hiroshi^*

来源：Chemical Communications, 2012, 48(84): 10398-10400.

DOI：10.1039/c2cc35625b

We describe asymmetric intramolecular Friedel-Crafts alkylations with a DNA-based hybrid catalyst and propose a plausible binding model. This study shows promise for studying relationships between the helical chirality of DNA and enantioselectivity of the chemical reaction.

• 出版日期2012