An Unusual Independent 1D Metal-Organic Nanotube with Mesohelical Structure and 1D -> 2D Interdigitation

作者：Jin, Jun-Cheng; Wang, Yao-Yu^*; Liu, Ping; Liu, Rui-Ting; Ren, Chen; Shi, Qi-Zhen

来源：Crystal Growth & Design, 2010, 10(5): 2029-2032.

DOI：10.1021/cg901201s

• HELICAL COORDINATION POLYMER
• STRANDED MOLECULAR BRAID
• CRYSTAL-STRUCTURE
• MIXED-LIGANDS
• FRAMEWORK
• NETWORKS
• CHAINS
• ARCHITECTURE
• SERIES
• WATER

A novel one-dimensional (1D) metal organic nanotube {[Cd-2(ADC)(2)(bpp)(3)(H2O)](2)center dot 8H(2)O}(n) (MONT-1), based on mixed organic ligands, has been synthesized and characterized. MONT-1 presents the first independent 1D metal organic nanotube with mesohelical structure and a fascinating topology of 1D -> 2D interdigital architecture with side arms. This compound also exhibits high thermal stability and blue-shift emission with large intensity enhancement compared with that of the free ligand and can be explored for potential blue luminescent materials.

• 出版日期2010-5
• 单位西北大学