Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki-Miyaura coupling

作者:Urbaneja Xavier; Mercier Audrey; Besnard Celine; Kuendig E Peter
来源:Chemical Communications, 2011, 47(13): 3739-3741.
DOI:10.1039/c1cc10347d

摘要

Access to planar chiral complexes has been sought by catalytic desymmetrisation of a prochiral complex via asymmetric Suzuki-Miyaura cross-coupling. High selectivities of up to 98% ee were achieved using a bulky chiral palladium catalyst.

  • 出版日期2011