A novel 2D polymeric structure of Cu-Na complex, in which phthalate gives seven coordination sites

作者：Liu XW; Xie CZ; Wang XQ^*; Shen GQ; Shen DZ

来源：Inorganic Chemistry Communications, 2003, 6(12): 1433-1435.

DOI：10.1016/j.inoche.2003.09.006

• crystal structure
• Cu-Na hetero-nuclear complex
• 2D coordination layer
• phthalate acid

A novel copper and sodium hetero-nuclear complex {[(H2O)Na](2)Cu(phth)(2)}(n) (phth = phthalate) was synthesized and its crystal structure has been determined by X-ray diffraction methods. The complex structure consists of two-dimensional (2D) infinite layers, in which it is first observed that one phthalate ligand coordinates to five metal ions and gives seven coordination sites.

• 出版日期2003-12
• 单位清华大学