A sonochemical method for the preparation of cadmium sulfide and cadmium selenide nanoparticles in aqueous solutions

作者：Kristl Matjaz; Ban Irena^*; Danc Anita; Danc Valerija; Drofenik Miha

来源：Ultrasonics Sonochemistry, 2010, 17(5): 916-922.

DOI：10.1016/j.ultsonch.2009.12.013

• Sonochemistry
• Nanoparticles
• Cadmium sulfide
• Cadmium selenide

Sonochemistry is a branch of chemistry where sound energy in the form of ultrasound is used to influence the course of reactions. A short-term, local increase in temperature occurs when the solutions and suspensions are irradiated by ultrasound. This happens because the substance absorbs the ultrasound waves. The purpose of this research was the synthesis of CdS and CdSe nanoparticles. We used cadmium sulfate hydrate (CdSO(4)center dot 8/3H(2)O), elemental S and Se. Aqueous solutions of NaOH, Na(2)SO(3) and EDTA were used as the solvents.
During the syntheses, we used a direct immersion ultrasound probe by vibracell. The device operates with a constant frequency of 20 kHz, with the possibility to change the amplitude and with it the input of energy to the time unit. The products were characterized by X-ray powder diffraction (XRD), thermal analyses (TGA. SDTA) and TEM analyses.

• 出版日期2010-6