Nanocomposites of a nematic liquid crystal doped with magic-sized CdSe quantum dots

作者：Mirzaei Javad; Urbanski Martin; Yu Kui; Kitzerow Heinz S; Hegmann Torsten^*

来源：Journal of Materials Chemistry, 2011, 21(34): 12710-12716.

DOI：10.1039/c1jm11832c

• CdSe quantum dots
• Core composition
• Deep traps
• Dielectric anisotropies
• Director fields
• Electro-optic properties
• Elevated concentrations
• Glass slides
• Homeotropic alignment
• Myristic acid
• Nematic director
• Nematic hosts
• Nematic phase
• Planar alignment
• Planar orientation
• Randomly distributed
• Splay elastic constants
• Surface functionalities

We here report on the optical, alignment and electro-optic properties of a nematic liquid crystal affected by the presence of semiconductor CdSe magic-sized nanocrystals (MSNCs). Three single-sized CdSe samples were tested, exhibiting bright bandgap photoluminescence (PL) with lambda(max) approximate to 463 nm and similar to 10 nm full width at half-maximum (fwhm). The three quantum dot (QD) samples were passivated with a monolayer of myristic acid. Two of them (QD1 and QD2) only vary in the amount of defects as indicated by different bandgap and deep trap PL. The third MSNC sample (QD3) is compositionally different, doped with Zn. These MSNCs with almost identical sizes were doped at different concentrations (1-5 wt%) into the nematic phase of 5-n-heptyl-2-(4-n-octyloxyphenyl)-pyrimidine (LC1). Only QD3 showed the formation of birefringent stripes surrounded by areas of homeotropic alignment between plain glass slides at all concentrations as observed for many other nanoparticle-doped nematic liquid crystals reported earlier by our group. In polyimide-coated glass slides favouring planar orientation of the nematic director, planar alignment was observed. Surprisingly, only the Zn-doped magic-sized QD3 quantum dots (CdSe@Zn) significantly lower the dielectric anisotropy as well as the splay elastic constant of the nematic host, despite identical size and surface functionality, which highlights the tremendous effect of the nanocrystal core composition on the electro-optic properties of the nematic host. In addition, fluorescence confocal (polarizing) microscopy studies show the director field within and around the birefringent stripes and confirm locally elevated concentrations or aggregates of the MCNC that are otherwise randomly distributed in the nematic host.

• 出版日期2011