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摘要
Novel Mn4+-activated far-red emitting SrMg2La2W2O12(SMLW) phosphors were prepared by a conventional high-temperature solid-state reaction method. The SMLW:Mn4+phosphors showed a broad excitation band peaking at around 344 nm and 469 nm in the range of 300-550 nm. Under 344 nm near-ultraviolet light or 469 nm blue light, the phosphors exhibited a far-red emission band in the 650-780 nm range centered at about 708 nm. The optimal Mn4+doping concentration in the SMLW host was 0.2 mol% and the CIE chromaticity coordinates of SMLW:0.2% Mn4+phosphors were calculated to be (0.7322, 0.2678). In addition, the influences of crystal field strength and nephelauxetic effect on the emission energy of Mn4+ions were also investigated. Moreover, the internal quantum efficiency of SMLW:0.2% Mn4+phosphors reached as high as 88% and they also possessed good thermal stability. Specifically, the emission intensity at 423 K still maintained about 57.5% of the initial value at 303 K. Finally, a far-red light-emitting diode (LED) lamp was fabricated by using a 365 nm near-ultraviolet emitting LED chip combined with the as-obtained SMLW:0.2% Mn4+far-red phosphors.
This journal is
- 出版日期2018
- 单位太原理工大学
