科研之友
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摘要
The rutheniumcarbamate complex derived from3-trimethoxysilyl-1propyl amine and carbon dioxidewas found to be a novel catalyst for the oxidative cyanation of aromatic and cyclic tertiary amines to corresponding alpha-amino nitriles in high to excellent yields by using hydrogen peroxide and molecular oxygen as enviro-economic oxidants. The developed protocol suggested an efficient alternative for recycling carbon dioxide.
- 出版日期2013
